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Charge transfer interactions of a Ru(II) dye complex and related ligand molecules adsorbed on Au(111)
A. J. Britton et al, J. Chem. Phys. 135, 164702(2011)

A single centre water splitting dye complex adsorbed on rutile TiO2(110): Photoemission, x-ray absorption and optical spectroscopy
M. Weston et al, J. Chem. Phys. 135, 114703(2011)

Vernier templating and synthesis of a 12-porphyrin nano-ring
M. C. O’Sullivan et al, Nature 469, 72 (2011)

Charge transfer dynamics of model charge transfer centres of a multi-centre water splitting dye complex on rutile TiO₂(110)
M. Weston et al, J. Chem. Phys. 134, 054705 (2011)

Single molecule magnets on a gold surface: in-situ electrospray deposition, X-ray absorption and
photoemission
A. Saywell et al, Nanotechnology 22, 075704 (2011)

Conformation and Packing of Porphyrin Polymer Chains Deposited Using Electrospray on a Gold Surface
A. Saywell et al, Angewandte Chemie-Int. Ed. 49, 9136 (2010)

Self-assembled aggregates formed by single-molecule magnets on a gold surfaces
A. Saywell et al, Nature Communications. 1, 75 (2010)

Charge transfer between the Au(111) surface and adsorbed C₆₀: Resonant photoemission and new core-hole decay channels
A. Britton et al, J. Chem. Phys. 133, 094705 (2010)

X-ray absorption and photoemission spectroscopy of zinc-protoporphyrin adsorbed on rutile TiO₂110) prepared by in situ electrospray deposition
A. Rienzo et al, J. Chem. Phys. 132, 084703 (2010)

Adsorption of PTCDI on Au(111): photoemission and scanning tunneling microscopy
J. N. O'Shea et al, Surf. Sci. 603, 3094 (2009)

Adsorption of a Ru(II) dye complex on the Au(111) surface: Photoemission and scanning tunneling microscopy
L. C. Mayor et al, J. Chem. Phys. 130 164704 (2009)

Photoemission, resonant photoemission and X-ray absorption of a Ru(II) complex adsorbed on rutile TiO₂(110) prepared by in-situ electrospray deposition
L. C. Mayor et al, J. Chem. Phys. 129, 114701 (2008)

Electrospray Deposition of C₆₀ on a Hydrogen-Bonded Supramolecular Network
A. Saywell et al, J. Phys. Chem. C 112, 7706 (2008)

Molecular damage in bi-isonicotinic acid adsorbed on rutile TiO₂(110)
J. N. O'Shea et al, Surf. Sci. 602, 1693 (2008)

Electrospray deposition of fullerenes in ultra-high vacuum: in situ scanning tunneling microscopy and photoemission spectroscopy
C. J Satterley et al, Nanotechnology 18, 455304 (2007)

Charge-Transfer Dynamics at Model Metal-Organic Solar Cell Surfaces
J. B. Taylor et al, J. Phys. Chem. C, 111, 16646 (2007)

Adsorption and charge transfer dynamics of bi-isonicotinic acid on Au(111)
J. B. Taylor et al, J. Chem. Phys. 127, 134707 (2007)

Bulk electronic structure of K₃C₆₀ as revealed by soft x-rays
T. Käämbre et al, Phys. Rev. B 75, 195432 (2007)

Electrospray deposition of carbon nanotubes in vacuum
J. N. O'Shea et al, Nanotechnology 18, 035707 (2007)

Electrospray deposition in vacuum
J. C. Swarbrick et al, Appl. Surf. Sci. 252, 5622 (2006)

Intramolecular vibronic dynamics in molecular solids: C₆₀
L. Kjeldgaard et al, Phys. Rev. B 72, 205414 (2005)

Phase and molecular orientation in metal-free phthalocyanine films on conducting glass: Characterization of two deposition methods
Y. Alfredsson et al, Thin Solid Films 493, 13 (2005)

Molecular orbitals tell the story
J. N. O'Shea, Science 310, 453 (2005)

(C₆H₅)₅C₆0H at Si(111)-(7x7) and Ag : Si(111)-(√3 x √3)R30° surfaces
M. A. Phillips et al, Phys. Rev. B 72, 075426 (2005)

Square, Hexagonal and Row Phases of PTCDA and PTCDI on Ag-Si(111) √3 x √3 R 30°
J. C. Swarbrick et al, J. Phys. Chem. B 109, (2005)

Bulk and surface charge states of K₃C₆₀
J. Schiessling et al, Phys. Rev. B 71, 165420 (2005)

Molecular ordering in isonicotinic acid on rutile TiO₂(110) investigated with valence band photoemission
J. N. O'Shea et al, J. Chem. Phys. 121, 10203 (2004)

nsulating surface layer on single crystal K₃C₆₀
J. Schiessling et al, Eur. Phys. J B 41, 435 (2004)

X-ray photoelectron spectroscopy of fluorescein adsorbed on model solar-cell surfaces
J. N. O'Shea et al, Surf. Sci. 548, 317 (2004)

Competing interactions of noble metals and fullerenes with the Si(111)7×7 surface
J. N. O'Shea et al, J. Chem. Phys. 119, 13046 (2003)

Excited-state charge transfer dynamics in systems of aromatic adsorbates on TiO₂ studied with resonant core tenchniques
J. Schnadt et al, J. Chem. Phys. 119, 12462 (2003)

Structural study of adsorption of isonicotinic acid and related molecules on rutile TiO₂(110) II: XPS
J. Schnadt et al, Surf. Sci. 544, 74 (2003)

Structural study of adsorption of isonicotinic acid and related molecules on rutile TiO₂(110) I: XAS and STM
J. Schnadt et al, Surf. Sci. 540, 39 (2003)

Alignment of valence photoemission, x-ray absorption, and substrate density of states for an adsorbate on a semiconductor surface
J. Schnadt et al, Phys. Rev. B 67, 235420 (2003)

Experimental evidence for sub-3-fs charge transfer from an aromatic adsorbate to a semiconductor
J. Schnadt et al, Nature 418, 620 (2002)

Colloidal particle foams: Templates for Au nanowire networks?
J. N. O'Shea et al, App. Phys. Lett. 81, 5039 (2002)

Angle-dependent valence photoemission study of pure phase K₃C₆₀
J. Schiessling et al, AIP Conf. Proc., 591, 131 (2001)

Beamline-induced chromium structure in carbon K-edge absorption spectra
J. Schnadt et al, Nucl. Instr. And Meth. In Phys. Res. B. 184, 609 (2001)

Hydrogen-bond induced surface core-level shift in pyridinecarboxylic acids
J. N. O'Shea et al, Surf. Sci. 486, 157 (2001)

Hydrogen-bond induced surface core-level shift in isonicotinic acid
J. N. O'Shea et al, J. Phys. Chem. 105, 1917 (2001)

Oxidation states at alkali-metal-doped Ni(110)-O surfaces
A. F. Carley et al, Phys. Chem. Chem. Phys. 3, 274 (2001)

X-ray photoelectron spectroscopy of low surface concentration mass-selected Ag clusters
J. N. O’Shea et al, J. Chem. Phys. 113, 9233 (2000)

N1s x-ray absorption study of the bonding interaction of bi-isonicotinic acid adsorbed on rutile TiO₂(110)
P. Persson et al, J. Chem. Phys. 112, 3945 (2000)

Alkali metal reactions with Ni(110)–O and NiO(100) surfaces
A. F. Carley et al, Surf. Sci. 454–456, 141 (2000)

The formation and characterisation of Ni³⁺, an X-ray photoelectron spectroscopic investigation of potassium-doped Ni(110)–O
A. F. Carley et al, Surf. Sci. 440, L868 (1999)



Charge transfer dynamics of model charge transfer centres of a multi-centre water splitting dye complex on rutile TiO₂(110) M. Weston et al, J. Chem. Phys.(2011) This paper is our first relating to the photocatalytic splitting of water molecules by a larger, multi-centre organometallic complex adsorbed on a titanium dioxide surface. In this experiment, carried out using in-situ electrospray deposition at the Maxlab synchrotron in Sweden, we take a look at the charge transfer dynamics of excited electrons on these molecules. Using the core-hole clock implementation of resonant photoemission, we can measure the charge transfer time for electrons going from previously unoccupied molecular orbitals on the dye into the conduction band of the oxide substrate. Hotel de Paris The legendary 5* Hôtel de Paris will hopefully be our home for the night, providing access to the health spa, beach club and the Casino. The hotel's underground car park will take care of the cars. Monte-Carlo Run The 2011 Monte-Carlo Run is now in the planning stage. Participation is by invitation only. The idea is to drive to Monaco and meet up in the Place du Casino in Monte-Carlo, before relaxing in the Monte Carlo Beach Club, Thermes Marins spa, and in the evening the Casino de Monte Carlo. Molecularspray Ltd Molecularspray provides complete solutions for the deposition of fragile, non-volatile molecules at surfaces under UHV conditions, with a powerful portable UHV-compatible electrospray deposition system and compact high-voltage power supplies. I am currently acting as a scientific consultant to Molecularspray through University of Nottingham Consultants.
Publications Charge transfer interactions of a Ru(II) dye complex and related ligand molecules adsorbed on Au(111) A. J. Britton et al, J. Chem. Phys. 135, 164702(2011) A single centre water splitting dye complex adsorbed on rutile TiO2(110): Photoemission, x-ray absorption and optical spectroscopy M. Weston et al, J. Chem. Phys. 135, 114703(2011) Vernier templating and synthesis of a 12-porphyrin nano-ring M. C. O’Sullivan et al, Nature 469, 72 (2011) Charge transfer dynamics of model charge transfer centres of a multi-centre water splitting dye complex on rutile TiO₂(110) M. Weston et al, J. Chem. Phys. 134, 054705 (2011) Single molecule magnets on a gold surface: in-situ electrospray deposition, X-ray absorption and photoemission A. Saywell et al, Nanotechnology 22, 075704 (2011) Conformation and Packing of Porphyrin Polymer Chains Deposited Using Electrospray on a Gold Surface A. Saywell et al, Angewandte Chemie-Int. Ed. 49, 9136 (2010) Self-assembled aggregates formed by single-molecule magnets on a gold surfaces A. Saywell et al, Nature Communications. 1, 75 (2010) Charge transfer between the Au(111) surface and adsorbed C₆₀: Resonant photoemission and new core-hole decay channels A. Britton et al, J. Chem. Phys. 133, 094705 (2010) X-ray absorption and photoemission spectroscopy of zinc-protoporphyrin adsorbed on rutile TiO₂110) prepared by in situ electrospray deposition A. Rienzo et al, J. Chem. Phys. 132, 084703 (2010) Adsorption of PTCDI on Au(111): photoemission and scanning tunneling microscopy J. N. O'Shea et al, Surf. Sci. 603, 3094 (2009) Adsorption of a Ru(II) dye complex on the Au(111) surface: Photoemission and scanning tunneling microscopy L. C. Mayor et al, J. Chem. Phys. 130 164704 (2009) Photoemission, resonant photoemission and X-ray absorption of a Ru(II) complex adsorbed on rutile TiO₂(110) prepared by in-situ electrospray deposition L. C. Mayor et al, J. Chem. Phys. 129, 114701 (2008) Electrospray Deposition of C₆₀ on a Hydrogen-Bonded Supramolecular Network A. Saywell et al, J. Phys. Chem. C 112, 7706 (2008) Molecular damage in bi-isonicotinic acid adsorbed on rutile TiO₂(110) J. N. O'Shea et al, Surf. Sci. 602, 1693 (2008) Electrospray deposition of fullerenes in ultra-high vacuum: in situ scanning tunneling microscopy and photoemission spectroscopy C. J Satterley et al, Nanotechnology 18, 455304 (2007) Charge-Transfer Dynamics at Model Metal-Organic Solar Cell Surfaces J. B. Taylor et al, J. Phys. Chem. C, 111, 16646 (2007) Adsorption and charge transfer dynamics of bi-isonicotinic acid on Au(111) J. B. Taylor et al, J. Chem. Phys. 127, 134707 (2007) Bulk electronic structure of K₃C₆₀ as revealed by soft x-rays T. Käämbre et al, Phys. Rev. B 75, 195432 (2007) Electrospray deposition of carbon nanotubes in vacuum J. N. O'Shea et al, Nanotechnology 18, 035707 (2007) Electrospray deposition in vacuum J. C. Swarbrick et al, Appl. Surf. Sci. 252, 5622 (2006) Intramolecular vibronic dynamics in molecular solids: C₆₀ L. Kjeldgaard et al, Phys. Rev. B 72, 205414 (2005) Phase and molecular orientation in metal-free phthalocyanine films on conducting glass: Characterization of two deposition methods Y. Alfredsson et al, Thin Solid Films 493, 13 (2005) Molecular orbitals tell the story J. N. O'Shea, Science 310, 453 (2005) (C₆H₅)₅C₆0H at Si(111)-(7x7) and Ag : Si(111)-(√3 x √3)R30° surfaces M. A. Phillips et al, Phys. Rev. B 72, 075426 (2005) Square, Hexagonal and Row Phases of PTCDA and PTCDI on Ag-Si(111) √3 x √3 R 30° J. C. Swarbrick et al, J. Phys. Chem. B 109, (2005) Bulk and surface charge states of K₃C₆₀ J. Schiessling et al, Phys. Rev. B 71, 165420 (2005) Molecular ordering in isonicotinic acid on rutile TiO₂(110) investigated with valence band photoemission J. N. O'Shea et al, J. Chem. Phys. 121, 10203 (2004) nsulating surface layer on single crystal K₃C₆₀ J. Schiessling et al, Eur. Phys. J B 41, 435 (2004) X-ray photoelectron spectroscopy of fluorescein adsorbed on model solar-cell surfaces J. N. O'Shea et al, Surf. Sci. 548, 317 (2004) Competing interactions of noble metals and fullerenes with the Si(111)7×7 surface J. N. O'Shea et al, J. Chem. Phys. 119, 13046 (2003) Excited-state charge transfer dynamics in systems of aromatic adsorbates on TiO₂ studied with resonant core tenchniques J. Schnadt et al, J. Chem. Phys. 119, 12462 (2003) Structural study of adsorption of isonicotinic acid and related molecules on rutile TiO₂(110) II: XPS J. Schnadt et al, Surf. Sci. 544, 74 (2003) Structural study of adsorption of isonicotinic acid and related molecules on rutile TiO₂(110) I: XAS and STM J. Schnadt et al, Surf. Sci. 540, 39 (2003) Alignment of valence photoemission, x-ray absorption, and substrate density of states for an adsorbate on a semiconductor surface J. Schnadt et al, Phys. Rev. B 67, 235420 (2003) Experimental evidence for sub-3-fs charge transfer from an aromatic adsorbate to a semiconductor J. Schnadt et al, Nature 418, 620 (2002) Colloidal particle foams: Templates for Au nanowire networks? J. N. O'Shea et al, App. Phys. Lett. 81, 5039 (2002) Angle-dependent valence photoemission study of pure phase K₃C₆₀ J. Schiessling et al, AIP Conf. Proc., 591, 131 (2001) Beamline-induced chromium structure in carbon K-edge absorption spectra J. Schnadt et al, Nucl. Instr. And Meth. In Phys. Res. B. 184, 609 (2001) Hydrogen-bond induced surface core-level shift in pyridinecarboxylic acids J. N. O'Shea et al, Surf. Sci. 486, 157 (2001) Hydrogen-bond induced surface core-level shift in isonicotinic acid J. N. O'Shea et al, J. Phys. Chem. 105, 1917 (2001) Oxidation states at alkali-metal-doped Ni(110)-O surfaces A. F. Carley et al, Phys. Chem. Chem. Phys. 3, 274 (2001) X-ray photoelectron spectroscopy of low surface concentration mass-selected Ag clusters J. N. O’Shea et al, J. Chem. Phys. 113, 9233 (2000) N1s x-ray absorption study of the bonding interaction of bi-isonicotinic acid adsorbed on rutile TiO₂(110) P. Persson et al, J. Chem. Phys. 112, 3945 (2000) Alkali metal reactions with Ni(110)–O and NiO(100) surfaces A. F. Carley et al, Surf. Sci. 454–456, 141 (2000) The formation and characterisation of Ni³⁺, an X-ray photoelectron spectroscopic investigation of potassium-doped Ni(110)–O A. F. Carley et al, Surf. Sci. 440, L868 (1999)