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Until 1985, the chemical element Carbon was only known
to exist in two forms - diamond and graphite. This changed when
Kroto and co-workers discovered an entirely new form of carbon, which
became known as C60 or the fullerene molecule. (This
discovery later led to their award of the 1996 Nobel Prize in Chemistry.)
The original discovery of C60 was in the soot produced from
the laser ablation of graphite. Since then, other methods of production
have been developed. It is also thought that isolated C60 molecules
may be found in stars and interstellar media.
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The fullerene molecule consists
of 60 carbon atoms arranged in pentagons and hexagons, very like
in a standard football (soccerball). It is also known as Buckminster
Fullerene due to the resemblance of this shape to the geodesic domes
designed and built by the architect R Buckminster Fuller.
If you have enabled the
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It was soon discovered that C60 is not the
only ball-like carbon molecule possible (although it is the most stable
and the most dominant). The rugby-ball shaped C70 molecule
is another possibility.
It was not until the early 1990s that fullerenes could
be synthesised in large enough quantities for significant research in
this field to be undertaken. Since then, fullerenes have been prepared
in gas and solid phases, in inert gas matrices, in a range of different
solutions, as fulleride salts and in polymerised states. Some solids intercalated
with alkali metals are superconductors. This means that at temperatures
below the transition temperature Tc, a current can flow
with no resistance. Even though Tc in the fulleride
superconductors is at most 40 K (-233°C) it is only the second-known class
of superconductors in which Tc is high enough for potential
applications to be a possibility. It is perhaps surprising that some intercalated
solids are insulators, i.e. are highly resistant to current flow.
Many of the early experimental results on C60
were unreliable because the samples tended to be small and highly contaminated.
However, in the last few years a very large number of reliable experimental
results have become available. Despite a high level of activity, many
of these results are either unexplained or subject to controversy. Analysis
of the data is far from straightforward. One major difficulty is due to
the interdisciplinary nature of the subject. The vast majority of experimental
investigations are carried out by Chemists, but the processes giving rise
to the experimental observations are driven by Physics. We are currently
trying to resolve these difficulties by combining the expertise of Chemists
and Physicists
In nanotechnology, the potential applications of carbon
nanotubes (formed by combining hexagonal rings of carbon atoms
only, rather than hexagons and pentagons as in C60)
for very small electronic devices are currently the subject of
much activity.
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