
Darren Walsh
Lecturer in Chemistry and Chemical Engineering [DICE], Faculty of Science
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Biography
Dr. Darren Walsh obtained his B.Sc in Analytical Science from Dublin City University in 1997 and his M.Sc. in Analytical Chemistry from the Institute of Technology Tallaght, Dublin in 1999. In 2002, he obtained his PhD in Physical Chemistry from Dublin City University where he studied heterogeneous electron transfer dynamics across the electrode/monolayer interface using ultrafast electrochemical techniques with Prof. Robert Forster. He then spent one year as a postdoctoral researcher at Dublin City University, where he extended his studies of charge transfer dynamics to redox polymers at electrode surfaces. This work was carried out in collaboration with Prof. Adam Heller at the University of Texas at Austin.
In 2003, Dr. Walsh moved to the University of Texas at Austin to take up a position as a postdoctoral researcher with Prof. Allen J. Bard where he began his work on electrocatalysis and scanning electrochemical microscopy. In 2005, he moved to the University of Newcastle upon Tyne to take up a position as a Lecturer in Physical Chemistry. In 2007, he joined the School of Chemistry at the University of Nottingham as a DICE (Driving Innovation through Chemistry and Chemical Engineering) Lecturer.
Expertise Summary
The Walsh research group is particularly interested in the development and applications of new nanostructured electrode surfaces, particularly in scanning electrochemical microscopy (SECM). SECM is a scanning probe technique that involves positioning an ultramicroelectrode tip very close to a substrate while in contact with an electroactive species in solution. The tip signal is the faradaic current generated by electrolysis of the electroactive solution species, which is altered as the tip approaches the substrate. By scanning the tip above the substrate, it is possible to obtain information about the substrate in terms of both topography and reactivity. Current SECM projects in the lab include the development of new probes for SECM that will increase its resolution as well as broadening its applications, e.g., we are currently developing new probes that will allow is to screen novel fuel cell catalysts using SECM. Other projects in the lab include the development and applications of nanostructured electrodes based on carbon nanotubes and nanofibres. These materials are particularly useful as supports for catalysts and we are investigating the impregnation and these materials with new catalytic materials.
Teaching Summary
My teaching within the School of Chemistry is primarily focused on Physical and Analytical Chemistry. I am the module convener for the following modules:
F12PAC - Principles of Analytical Chemistry
F12ERI - Equilibria, Rates and Interfaces
F13PSC - Professional Skills for Chemists
I also contribute lectures to:
F14ST1 - Special Topic in Chemistry
F11FIC - Frontiers in Chemistry
Selected Publications
LOVELOCK, K. R. J., COWLING, F. N., TAYLOR, A. W., LICENCE, P. and WALSH, D. A., 2010. Effect of viscosity on steady-state voltammetry and scanning electrochemical microscopy in room temperature ionic liquids. The Journal of Physical Chemistry: B. 114(13), 4442-4450 TAYLOR, AW, QIU, FL, HU, JP, LICENCE, P and WALSH, DA, 2008. Heterogeneous Electron Transfer Kinetics At The Ionic Liquid/Metal Interface Studied Using Cyclic Voltammetry And Scanning Electrochemical Microscopy Journal Of Physical Chemistry B. 112(42), 13292-13299 LIEW, SY, THIELEMANS, W and WALSH, DA, 2010. Electrochemical Capacitance Of Nanocomposite Polypyrrole/Cellulose Films Journal Of Physical Chemistry C. 114(41), 17926-17933 JOHNSON, L., THIELEMANS, W. and WALSH, D., 2010. Nanocomposite oxygen reduction electrocatalysts formed using bioderived reducing agents Journal of Materials Chemistry. VOL 20(NUMBER 9), 1737-1743